Download Aldol Reactions by Rainer Mahrwald PDF

By Rainer Mahrwald

Aldol Reactions offers a accomplished up to date assessment of aldol reactions including:

  • Application of other steel enolates
  • Catalytic aldol additions catalyzed via various Lewis acids and Lewis bases
  • Enantioselective direct aldol additions
  • Antibodies and enzyme catalyzed aldol additions
  • The contemporary competitive improvement of organocatalyzed aldol additions.

The energy of every approach is validated through numerous functions in overall synthesis of ordinary items. the professionals and cons of those methodologies with reference to stereoselectivity, regioselectivity and alertness in overall synthesis of ordinary items are mentioned. nice significance is determined to the various chances of the handbook of aldol response to put in required configurations in complex usual product synthesis.

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R1-CHO Method B: 1. 0 equiv. TiCl4, 2. 1 equiv i-Pr2NEt, 3. 12 Oxazolidinethione-based syn-selective aldol additions O O 1. TiCl4 2. i-Pr2NEt 3. r. r. = 95:5 O CO2Me N i-Pr R N O i-Pr O CO2Et 1. TiCl4 2. R-CHO 3. r. r. 14). 4 Titanium Enolates 49 O O O OH X O O O O 1. Et3N 2. i-Pr2 NEt 3. 44 For the development and application of chiral oxadiazinones in enantioselective titanium enolate aldol reactions see Casper et al. 45 Chiral titanium(IV) alkoxides were used for the synthesis of optically active β-hydroxy ketones.

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